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Preparation of star-shaped functionalized polylactides by metal porphyrin complexes as both catalysts and cocatalysts  期刊论文  

  • 编号:
    7fb7173a-0959-4f42-b112-07db0c3c0224
  • 作者:
  • 语种:
    英文
  • 期刊:
    JOURNAL OF PORPHYRINS AND PHTHALOCYANINES ISSN:1088-4246 2019 年 23 卷 9 期 (1020 - 1027) ; SEP
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  • 摘要:

    Several aluminum porphyrin complexes as catalysts and a copper porphyrin complex as a cocatalyst were prepared. These complexes were characterized by H-1 NMR and elemental analysis. These complexes arc used for L-lactide polymerization. The kinetic data of the polymerization using complex 2 as catalyst revealed that the polymeric rates were first-ordered in both the monomer and catalyst. There is a linear relationship between lactide conversion and the number-averaged molecular weight of PLA.

  • 推荐引用方式
    GB/T 7714:
    Li Dongni,Gao Bo,Duan Qian, et al. Preparation of star-shaped functionalized polylactides by metal porphyrin complexes as both catalysts and cocatalysts [J].JOURNAL OF PORPHYRINS AND PHTHALOCYANINES,2019,23(9):1020-1027.
  • APA:
    Li Dongni,Gao Bo,Duan Qian.(2019).Preparation of star-shaped functionalized polylactides by metal porphyrin complexes as both catalysts and cocatalysts .JOURNAL OF PORPHYRINS AND PHTHALOCYANINES,23(9):1020-1027.
  • MLA:
    Li Dongni, et al. "Preparation of star-shaped functionalized polylactides by metal porphyrin complexes as both catalysts and cocatalysts" .JOURNAL OF PORPHYRINS AND PHTHALOCYANINES 23,9(2019):1020-1027.
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