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Crystal structure of poly[[mu(3)-4,4''-(4,4''bipyridine-2,6-diyl)dibenzoato]{mu(2)-4-[6(4-carbo xyphenyl)-4,4''-bipyridin-4''- ium2-yl]benzoato}manganese(II)] hemihydrate] 期刊论文

编号：

d8bf5ba2-0cc2-435d-916f-8f285567029b
作者：

Li, Yaping(李亚萍)#^[1]Sun, Dajun(孙大军)*^[2]Ming, Julia^[3];Han, Liying^[4];Su, Guanfang^[1];
语种：

英文
期刊：

ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS ISSN：2056-9890 2014 年 70 卷 (M374 - +) ; NOV
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关键词：

crystal structure Mn complex metal-organic coordination polymer hydrogen bonds
摘要：

The title compound, {[Mn(C24H14N2O4)(C24H16N2O4)]center dot- 0.5H(2)O} n, was obtained by the reaction of manganese nitrate with the ligand 4,4''-(4,4''-bipyridine-2,6-diyl) dibenzoic acid under hydrothermal conditions. The water O atom is located on a twofold rotation axis. The Mn2+ ion is heptacoordinated by six O atoms and one N atom from the ligands. In this structure, the ligands adopts two different forms, one completely deprotonated and one with a protonated N atom (pyridinium) and a carboxylic acid function. In the crystal, N-H center dot center dot center dot O and O-H center dot center dot center dot O hydrogen bonds consolidate the packing, forming a three-dimensional framework.
推荐引用方式
GB/T 7714：

Li Yaping,Sun Dajun,Ming Julia, et al. Crystal structure of poly[[mu(3)-4,4''-(4,4''bipyridine-2,6-diyl)dibenzoato]{mu(2)-4-[6(4-carbo xyphenyl)-4,4''-bipyridin-4''- ium2-yl]benzoato}manganese(II)] hemihydrate] [J].ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS,2014,70:M374-+.
APA：

Li Yaping,Sun Dajun,Ming Julia,Han Liying,&Su Guanfang.(2014).Crystal structure of poly[[mu(3)-4,4''-(4,4''bipyridine-2,6-diyl)dibenzoato]{mu(2)-4-[6(4-carbo xyphenyl)-4,4''-bipyridin-4''- ium2-yl]benzoato}manganese(II)] hemihydrate] .ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS,70:M374-+.
MLA：

Li Yaping, et al. "Crystal structure of poly[[mu(3)-4,4''-(4,4''bipyridine-2,6-diyl)dibenzoato]{mu(2)-4-[6(4-carbo xyphenyl)-4,4''-bipyridin-4''- ium2-yl]benzoato}manganese(II)] hemihydrate]" .ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS 70(2014):M374-+.
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