首页 / 院系成果 / 成果详情页

Ring-opening polymerization of lactide using salen-aluminum complexes bearing Schiff-base ligands derived from cis-1,2-cyclohexanediamine 期刊论文

编号：

db86ab17-ca85-4cc5-a868-859af3be42b7
作者：

Cui, Yuan#^[1]Li, Dongni(李东霓)^[1,2]Gao, Bo(高波)*^[1,3]Zhou, Yuqi^[1];Chen, Li^[1];Qiu, Baoguo^[1];Li, Yanhui^[1,3];Duan, Qian(段潜)*^[1]Hu, Ninghai^[1,3];
语种：

英文
期刊：

JOURNAL OF COORDINATION CHEMISTRY ISSN：0095-8972 2016 年 69 卷 4 期 (656 - 667)
收录：
关键词：

Aluminum salen biodegradable lactide ring-opening polymerization
摘要：

Three aluminum complexes supported by salen ligands derived from cis-1,2-cyclohexanediamine and salicylaldehyde derivatives were synthesized. They were characterized by H-1, C-13 NMR spectra, and elemental analysis. X-ray diffraction analysis revealed that aluminum was in distorted square pyramidal geometry in 2. These complexes were employed as catalysts for the ring-opening polymerization (ROP) of L-lactide and rac-lactide. Complex 2 showed the highest activity among these complexes with isopropanol for the ROP of L-lactide and 3 showed the highest stereoselectivity for the ROP of rac-lactide attaining partially isotactic polylactide with a P-m of 0.75. The kinetic data of the polymerization utilizing 3 as catalyst showed that the polymeric rate was first order to the monomer and catalyst.
[GRAPHICS]
.
推荐引用方式
GB/T 7714：

Cui Yuan,Li Dongni,Gao Bo, et al. Ring-opening polymerization of lactide using salen-aluminum complexes bearing Schiff-base ligands derived from cis-1,2-cyclohexanediamine [J].JOURNAL OF COORDINATION CHEMISTRY,2016,69(4):656-667.
APA：

Cui Yuan,Li Dongni,Gao Bo,Zhou Yuqi,&Hu Ninghai.(2016).Ring-opening polymerization of lactide using salen-aluminum complexes bearing Schiff-base ligands derived from cis-1,2-cyclohexanediamine .JOURNAL OF COORDINATION CHEMISTRY,69(4):656-667.
MLA：

Cui Yuan, et al. "Ring-opening polymerization of lactide using salen-aluminum complexes bearing Schiff-base ligands derived from cis-1,2-cyclohexanediamine" .JOURNAL OF COORDINATION CHEMISTRY 69,4(2016):656-667.
条目包含文件：

文件类型：PDF,文件大小：

正在加载全文

未找到全文

浏览次数：20  下载次数：0

分享到：

浏览次数：20

下载次数：0

打印次数：0