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Rhodium-Catalyzed Oxidative Coupling Reaction of Isocyanides with Alcohols or Amines and Molecular Oxygen as Oxygen Source: Synthesis of Carbamates and Ureas 期刊论文

编号：

e8f5cf67-81f1-463e-9976-8ea999c568b8
作者：

Bu, XiuBin#^[1]Wang, Zhuo^[1];Wang, YuanHong^[1];Jiang, Tao(姜涛)*^[2]Zhang, Lu^[1];Zhao, YuLong(赵玉龙)*^[1]
语种：

英文
期刊：

EUROPEAN JOURNAL OF ORGANIC CHEMISTRY ISSN：1434-193X 2017 年 2017 卷 7 期 (1132 - 1138) ; FEB 17
收录：
关键词：

Rhodium Homogeneous catalysis Synthetic methods Oxidative insertion Isocyanides Carbamates Ureas
摘要：

The first Rh-catalyzed aerobic oxidative coupling reaction of isocyanides with alcohols or amines has been developed. The reaction takes place under very mild conditions, by using air as the terminal oxidant and oxygen-atom source. It provides a simple, efficient, and general method for the construction of N-arylcarbamates and ureas in an atom-economic manner. Moreover, the new mechanism, involving alpha-diazocarbonyl compounds as carbene precursors and a Rh-I/Rh-III catalytic cycle with oxygen, might open up new avenues in rhodium chemistry.
推荐引用方式
GB/T 7714：

Bu Xiu-Bin,Wang Zhuo,Wang Yuan-Hong, et al. Rhodium-Catalyzed Oxidative Coupling Reaction of Isocyanides with Alcohols or Amines and Molecular Oxygen as Oxygen Source: Synthesis of Carbamates and Ureas [J].EUROPEAN JOURNAL OF ORGANIC CHEMISTRY,2017,2017(7):1132-1138.
APA：

Bu Xiu-Bin,Wang Zhuo,Wang Yuan-Hong,Jiang Tao,&Zhao Yu-Long.(2017).Rhodium-Catalyzed Oxidative Coupling Reaction of Isocyanides with Alcohols or Amines and Molecular Oxygen as Oxygen Source: Synthesis of Carbamates and Ureas .EUROPEAN JOURNAL OF ORGANIC CHEMISTRY,2017(7):1132-1138.
MLA：

Bu Xiu-Bin, et al. "Rhodium-Catalyzed Oxidative Coupling Reaction of Isocyanides with Alcohols or Amines and Molecular Oxygen as Oxygen Source: Synthesis of Carbamates and Ureas" .EUROPEAN JOURNAL OF ORGANIC CHEMISTRY 2017,7(2017):1132-1138.
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